QinetiQ Group plc and Ricardo plc are developing a new battery system for hybrid/electric vehicles that uses a unique lithium chemistry. The U.K. partners say QinetiQ’s lithium-iron sulfide-based cell chemistry and Ricardo’s latest battery management system is less expensive, safer, better performing and easier to manufacture than competitive lithium-ion units.
The companies, which previously had partnered on the Efficient-C hybrid concept program, are showcasing the new technology in a 2-kW demonstration pack that was developed under the U.K. Energy Saving Trust Low Carbon R&D program. More than $3 million in funding for the project came from the U.K. Dept. for Transport under the Energy Saving Trust Low Carbon R&D program.
The new pack has been fitted into the Efficient-C’s four-year-old, diesel-electric hybrid concept that is based on a Citroen Berlingo.
The battery’s iron sulfide replaces more expensive, heavier metals such as cobalt, nickel and manganese used in the cathodes of current lithium-ion batteries. Cathodes made of Li-iron sulfide have about twice the theoretical energy density of more conventional lithium chemistries. In addition, iron-sulfide cathodes have less resistance to lithium transport, thus don’t require the extra processing of other designs, according to the developers. Weight has been reduced 20% vs. the 2-kW lithium-ion pack used in the Efficient-C concept.
The battery is controlled by Ricardo’s flexible battery-management system that can handle a range of cell types and configurations. It also can be used to conduct a variety of tests regarding voltage, energy, climate conditions, drive cycle, manufacturability and potential faults.
During internal testing, the batteries have demonstrated 50% faster discharge rates and an operating life of 1,000 charge/discharge cycles, according to the partners. QinetiQ now is working with local universities to optimize electrolyte additives and cathode composition to improve the cell’s energy density and extend cycle life.
With its high charge/discharge capabilities, the chemistry is well suited for hybrid-electric architectures, including plug-in and extended-range systems. But the partners say expected improvements will allow the technology to be adapted to all-electric systems too.
QinetiQ was formed in 2001 as an offshoot of the former U.K. Defence Evaluation and Research Agency military research group. It currently supplies traditional lithium-ion battery systems to military customers.